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Preparation of Cyanoguanidine and Ethylcyanamide Complexes of Ruthenium(II) and Osmium(II)

✍ Scribed by Gabriele Albertin; Stefano Antoniutti; Jesús Castro

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
225 KB
Volume
2009
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES

Osmium(II) and Ruthenium(II) Arene Malto
Osmium(II) and Ruthenium(II) Arene Maltolato Complexes: Rapid Hydrolysis and Nucleobase Binding
✍ Anna F. A. Peacock; Michael Melchart; Robert J. Deeth; Abraha Habtemariam; Simon 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 475 KB

## Abstract Density functional calculations show that aquation of [Os(η^6^‐arene)(XY)Cl]^__n__+^ complexes is more facile for complexes in which XY=an anionic O,O‐chelated ligand compared to a neutral N,N‐chelated ligand, and the mechanism more dissociative in character. The O,O‐chelated XY=maltola