## Abstract **Summary:** Electrospinning of polymer blends offers the potential to prepare functional nanofibers for use in a variety of applications. This work focused on control of the internal morphology of nanofibers prepared by electrospinning polymer blends to obtain core‐sheath structures. P
Preparation of Core-Sheath Nanofibers from Conducting Polymer Blends
✍ Scribed by Ming Wei; Junseok Lee; Bongwoo Kang; Joey Mead
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 219 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Summary: Core‐sheath nanofibers with conductive polyaniline as the core and an insulating polymer as the sheath were prepared by electrospinning of blends of polyaniline with either polystyrene or polycarbonate. These unique core‐sheath structures offer potential in a number of applications including nanoelectronics. When polyaniline was blended with poly(methyl methacrylate) and poly(ethylene oxide), only isolated domains of polyaniline in beadlike structures were formed. The phase morphology of electrospun fibers is thought to be dependent on the high‐surface tension of the solution and the molecular weight of the polymers. Incompatibility of the polymers and low molecular weight of compositions played a key role in the formation of core‐sheath structures, as opposed to co‐continuous morphologies.
TEM image of electrospun polyaniline/polystyrene nanofiber after staining by OsO~4~. The dark regions are polyaniline.
magnified imageTEM image of electrospun polyaniline/polystyrene nanofiber after staining by OsO~4~. The dark regions are polyaniline.
📜 SIMILAR VOLUMES
## Abstract **Summary:** Uniform core‐sheath nanofibers are prepared by electrospinning a water‐in‐oil emulsion in which the aqueous phase consists of a poly(ethylene oxide) (PEO) solution in water and the oily phase is a chloroform solution of an amphiphilic poly(ethylene glycol)‐poly(L‐lactic aci