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Preparation of cis- and trans-1,2-Diphenyl-1,2-cyclohexanediol 1

✍ Scribed by TOMBOULIAN, PAUL

Book ID
126783884
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
641 KB
Volume
26
Category
Article
ISSN
0022-3263

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Stereochemistry of the rearrangement of
Stereochemistry of the rearrangement of cis- and trans-1,2-divinyl-1,2-cyclohexanediols
✍ Elliot N. Marvell; William Whalley πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 178 KB

Rearrangement of 1,2-divinyl-1,2-cyclohexanediol (I) was shown by Coda, et al (1) to give l-bicyclo[5.3.O]decen-2-one (II). We had made the ssme observation independently (2), but had also found that under milder conditions 7-hydroxybicyclo[5.3,0] decsn-2-one (III) can be isolated in good yield. In