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Preparation of Chiral Homoannularly Bridged N,P-Ferrocenyl Ligands by Intramolecular Coupling of 1,5-Dilithioferrocenes and Their Application in Asymmetric Allylic Substitution Reactions

✍ Scribed by Shin-ichi Fukuzawa; Masahisa Yamamoto; Mitsuteru Hosaka; Satoshi Kikuchi


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
248 KB
Volume
2007
Category
Article
ISSN
1434-193X

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Synthesis of Phosphanyl Sulfoximines Thr
✍ Fabien Lemasson; Hans-Joachim Gais; Jan Runsink; Gerhard Raabe πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 511 KB

## Abstract The intermolecular phospha‐Michael reaction of cyclic and acyclic alkenyl sulfoximines proceeds readily and yields the corresponding phosphanyl sulfoximines in good yield. The asymmetric induction provided by sulfoximine group in C–P bond formation is apparently only low. The configurat