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Preparation of Chiral 7,7′-Disubstituted BINAPs for Rh-Catalyzed 1,4-Addition of Arylboronic Acids.

✍ Scribed by Wei-Cheng Yuan; Lin-Feng Cun; Liu-Zhu Gong; Ai-Qiao Mi; Yao-Zhong Jiang

Book ID: 101973538
Publisher: John Wiley and Sons
Year: 2005
Weight: 35 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200519035

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## Abstract A new family of benzene‐based chiral heterodisulfoxide ligands **L1**–**L5** was synthesized in a single step. These disulfoxide ligands were applied in the rhodium‐catalyzed asymmetric 1,4‐addition of arylboronic acids to chromenones. The addition of diverse arylboronic acids to chrome