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Preparation of Carboxylic Acids by the Carboxylation Reaction

✍ Scribed by LEVERING, D. R.; GLASEBROOK, A. L.


Book ID
121461107
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
435 KB
Volume
23
Category
Article
ISSN
0022-3263

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Resolution of racemic carboxylic acid de
✍ Dieter Seebach; Georg Jaeschke; Konstanze Gottwald; Keiji Matsuda; Roberto Formi πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 909 KB

The Lewis-acid mediated transfer of an alkoxide ligand from the chiral ligand sphere of Ti-TADDOLates ! to cyclic carboxylic acid derivatives is described. The kinetic resolution of dioxolanones, azlactones and biaryl lactones by the Ti-TADDOLates affords, after recrystallization, ester products in