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Preparation of bis[palladacycles] and application to asymmetric aza-Claisen rearrangement of allylic imidates

✍ Scribed by Jahyo Kang; Kyoung Han Yew; Tae Hyung Kim; Dae Hyuk Choi

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 248 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02439-5

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✦ Synopsis

A variety of optically active bis[palladacycles] 1-3 were prepared from ferrocene. The synthetic application of these chiral catalysts in asymmetric aza-Claisen rearrangement of allylic imidates was carried out with high enantioselectivity.

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