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Preparation of benzoate esters of morphine and its derivatives

✍ Scribed by Béni, Szabolcs; Tóth, Gergő; Noszál, Béla; Hosztafi, Sándor


Book ID
120080643
Publisher
Springer Vienna
Year
2012
Tongue
English
Weight
546 KB
Volume
143
Category
Article
ISSN
0026-9247

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The efficient conversion of Hagemann's ester and its t-butyl analogue into dienol ethers and dienol esters, and reactions of the derived dienolates with electrophiles is described. Hagemann's ester-ethyl 2-methyl-4-oxocyclohex-2-ene-l-carboxylate & 1,2 -undergoes alkylation under equilibrating condi