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Preparation of Apoptotic Inducers, 2,2-Diphenyl-1,3,2-oxazaborolidin-5-ones, under Alkaline Conditions.

✍ Scribed by Benjamin Velasco-Bejarano; Jose Trujillo-Ferrara; Rene Miranda

Book ID
102001316
Publisher
John Wiley and Sons
Year
2007
Weight
25 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Enantioselective reduction of prochiral
Enantioselective reduction of prochiral ketones catalyzed by new (R)-4-(phenylmercapto)methyl-5,5-diphenyl-1,3,2-oxazaborolidine and bis-[(R,R)-5,5-diphenyl-1,3,2-oxazaborolidine methyl]disulfide from l-cystine
✍ Xingshu Li; Rugang Xie πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 175 KB

Two new optically active l~-amino alcohols 1 and 2 were prepared from Lcystine. The in situ formed chiral oxazaborolidines have been used in the enantioselective catalytic homogeneous borane reduction of prochiral ketones and diketones. The chiral secondary alcohols are obtained with moderate to goo