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Preparation of an Aquocobaloxime 1,3-Dienyl Complex and Its Diels−Alder Reactions in Water and Organic Solvents

✍ Scribed by Tucker, Carmen J.; Welker, Mark E.; Day, Cynthia S.; Wright, Marcus W.


Book ID
126212281
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
115 KB
Volume
23
Category
Article
ISSN
0276-7333

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✍ D.A. Brown; S.K. Chawla 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 512 KB

A comparison of the kinetics of substitution by phosphite ligands of dicarbonyliodo(qcyclo-hexa-1,3dienyl) and dicarbonyliodo(q-cyclo-hepta-1,3dienyl)iron complexes is reported. In all cases a dissociative mechanism is observed. The variation of rate with the size of the attached ring is in the sequ