Preparation of an acrylics-grafted polyester and its aqueous dispersion—mechanical properties of acrylics-grafted polyesters

✍ Scribed by Toshiyuki Shimizu; Shinya Higashiura; Masakatsu Ohguchi

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 179 KB
• Volume: 75
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(20000228)75:9<1149::aid-app8>3.0.co;2-m

✦ Synopsis

Mechanical properties of grafted polyesters were discussed. In the case of grafting of acrylics of more than 25% in the grafting product, mechanical properties of the grafting products decreased greatly compared with the raw polyester. The influence of the molecular structure of the grafted polyester was not observed. The effect of composition of the grafted polymers was discussed. Mechanical properties varied with the composition of the side chain. In the case of grafting onto aromatic polyesters, grafting of an aromatic unsaturated monomer improved the mechanical properties of the grafted polymer. On the other hand, in the case of grafting onto an aliphatic polyester, grafting of an aliphatic unsaturated monomer improved mechanical properties of the grafting polymer. We found that the grafting of the polymer having a high compatibility with the polyester improved the mechanical properties of the grafting products, from the determination of the compatibility of each polymer and the mechanical properties of the grafting products.