Glycals and 2-hydroxyglycals' are useful compounds because of their versatile reactivity, and l-nitro-2, l-sulfonyl-3, l-formyl-, and l-hydroxymethyl-glycals4 have been described. In seeking to prepare 1-cyanoglycals, 2,3,4,6-tetra-O-acetyl-l-bromo-Dgalactopyranosyl cyanide (1) and its D-arabino an
✦ LIBER ✦
Preparation of amidine derivatives from 1-cyano-d-galactal
✍ Scribed by László Somsák
- Book ID
- 102995300
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 269 KB
- Volume
- 286
- Category
- Article
- ISSN
- 0008-6215
No coin nor oath required. For personal study only.
✦ Synopsis
Recently we described [3] the transformation of the cyano group of several 1cyanoglycals [1,2] into various heterocycles in order to test them as glycosidase inhibitors. 1-Cyano-D-galactal triacetate (1) was also used by Banaszek for the synthesis
📜 SIMILAR VOLUMES
Acetylated 1-cyano and 1-cyano-2-hydroxy
✍
László Somsák
📂
Article
📅
1989
🏛
Elsevier Science
🌐
English
⚖ 129 KB
Preparation and Derivatives of Cyano-1,4
✍
Nelson, B. A.; Minsek, R. C.; Simon, J. I.; Underwood, D. L.
📂
Article
📅
1955
🏛
American Chemical Society
🌐
English
⚖ 306 KB
Synthesis of Amidines Derived from Phosp
✍
Francisco Palacios; Ana Maria Ochoa de Retana; Jaione Pagalday
📂
Article
📅
2003
🏛
John Wiley and Sons
⚖ 190 KB
Synthesis of Amidines Derived from Phosp
✍
Francisco Palacios; Ana María Ochoa de Retana; Jaione Pagalday
📂
Article
📅
2003
🏛
John Wiley and Sons
🌐
English
⚖ 136 KB
Ring D modifications of ellipticine. Par
✍
Adrian T. Boogaard; Upendra K. Pandit; Gerrit-Jan Koome
📂
Article
📅
1994
🏛
Elsevier Science
🌐
French
⚖ 666 KB
## This resulted in the formation of I-acetyl-andl-acetamido&nethylellipticine. Deprotonation of l-cyano-6methylellipticine under the infruence ofa Palladium catalyst leads to a new annelated cllipticine (9) . From the derivatives obtained. 9 showed the highest cywstatic activity.
Cyano-sugars. Part 3. Synthesis of 2-C-c
✍
Hall, Richard H.; Bischofberger, Karl; Brink, Abraham J.; de Villiers, Olaf G.;
📂
Article
📅
1979
🏛
Royal Society of Chemistry
⚖ 855 KB