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Preparation of Aldehydes from Alkenes by the Addition of Carbon Monoxide and Hydrogen with Cobalt Carbonyls as Intermediates

✍ Scribed by Adkins, Homer; Krsek, George


Book ID
127296263
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
508 KB
Volume
70
Category
Article
ISSN
0002-7863

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Synthesis of diethyl [carbonyl-11C]malon
✍ Julien Barletta; Farhad Karimi; Hisashi Doi; Bengt LΓ₯ngstrΓΆm πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 French βš– 134 KB

Rhodium-mediated carbonylation reaction was applied to synthesize diethyl [carbonyl-11 C]malonate using [ 11 C]carbon monoxide at low concentration. The synthesis was performed starting with ethyl diazoacetate, ethanol and the rhodium complex being made in situ by chloro(1,5-cyclooctadiene)rhodium(I