Preparation of a sterically hindered n-thiosulfinylaniline and its equilibrium with a novel heterocycle, 5h-1,2,3-dithiazole
✍ Scribed by Yoshio Inagaki; Renji Okazaki; Naoki Inamoto
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 158 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
During the course of our studies on the abnormal reactlons in poly-tbutylbenzene derlvatlves, 1) we have observed an interesting equilibrium between an N-thiosulfinylanlllne system (2)2) and its cyclic form, 5H-1,2,3dlthlazole (2) , 2 represents the first example of this heterocycllc system,
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## Abstract Metal salts of __S__‐alkyl‐__N__‐cyanodithioiminocarbonates 7 react as __electrophiles__ with hydrazine hydrate to form 5‐amino‐3‐mercapto‐1__H__‐1,2,4‐triazole 1. The novel 4‐cyanothiosemicarbazide 9 is proposed as the intermediate which cyclizes to the aromatic triazole. The rate dete
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v