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Preparation of a stationary phase with s-triazine ring embedded group for reversed phase high-performance LC

✍ Scribed by Yingyu Li; Peichun Dai; Yanxiong Ke; Yu Jin; Xinmiao Liang

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 264 KB
Volume: 33
Category: Article
ISSN: 1615-9306
DOI: 10.1002/jssc.201000056

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✦ Synopsis

Abstract

This paper describes the synthesis and chromatographic evaluation of a new polar‐embedded stationary phase, which utilized 2,4,6‐trichloro‐1,3,5‐triazine as the spacer. The resulting materials were characterized by elemental analysis, IR, and solid‐state ^13^C NMR. Empirical test mixtures were utilized to evaluate the column, and showed that it had good performance for basic compounds and high selectivity for polyaromatic hydrocarbons. Moreover, the novel stationary phase has unique property, especially in the separation of “homologous alkaloids” from natural products.

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