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Preparation of 3-hydroxyisoindolin-1-ones and o-acylbenzamides. A study of ring-chain tautomerism

✍ Scribed by Takehiko Nishio; Hiroshi Yamamoto

Book ID
112131263
Publisher
Journal of Heterocyclic Chemistry
Year
1995
Tongue
English
Weight
719 KB
Volume
32
Category
Article
ISSN
0022-152X

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✍ Frank G. Riddell; Martin Rogerson; Ferenc Fülöp; Gábor Bernáth 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

## Abstract Condensation of __cis__‐__2__‐aminomethylcyclohexanol with __p__‐nitrobenzaldehyde under mild conditions initially gives the imine as the kinetically controlled product. The imine undergoes a solid‐state rearrangement to the bicyclic tetrahydro‐1, 3‐oxazine. The kinetics of the rearrang