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Preparation of 2-alkylidene oxetanes: An investigation of the Paterno-Büchi reaction between aliphatic aldehydes and allenes

✍ Scribed by Amy R Howell; Rong Fan; Anh Truong

Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 233 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(96)02001-1

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✦ Synopsis

Preliminary results of an examination of factors influencing the stoichiometry and regioselectivity of the Paterno-Btlchi reaction between aliphatic aldehydes and nonsymmetrical allenes are divulged. Surprisingly little regioselectivity was seen with 3-methyl-l,2-butadiene (6); however, l-ethoxy-l,2-propadiene ( ) provided a single regioisomer.

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## Abstract For Abstract see ChemInform Abstract in Full Text.