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Preparation of 2: 3 Dimethyl Butadiene and Its Polymerisation to "Methyl Rubber"

✍ Scribed by John J. McHenry, Peter J. Drumm and William F. O'Connor


Book ID
125274285
Publisher
Royal Irish Academy
Year
1944-1945
Weight
849 KB
Volume
50
Category
Article
ISSN
0035-8983

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a-Methylene-y-and-64actones undergo facile ring opening with frimethylsilyl iodide to yield 2-(iodoethyl)propenoic acid and 2-(iodupropyl)propenoic acid respectively, which are methylated to afford the corresponding esters. Treatment of methyl-2-(iodoethyl)propenoate with base generates P-carbometho