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✦ LIBER ✦
Preparation of 1,2-O-isopropylidene derivatives of α-d-galactoseptanose, β-l-altroseptanose, and 3-O-methyl-α-d-guloseptanose
✍ Scribed by Graham E Driver; John D Stevens
- Book ID
- 108309281
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 142 KB
- Volume
- 334
- Category
- Article
- ISSN
- 0008-6215
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The title branched-trisaccharide derivatives (9 and 13) have been synthesised from methyl 2,3-O-(2-nitrobenzylidene)-a-L-rhamnopyranoside (2) using the 2nitrobenzylidene residue as a temporary blocking-group. Condensation of 2 with methyl (2,3,4-tri-O-acetyl-a-D-glucopyranosyl bromide)uronate afford