Preparation of 1-tert-Butyl-3-methyl-2-phenyl-Δ3-1,2-azaboroline and Utilization of Its Anion as a Complex Ligand Analogous to Cyclopentadienyl

Preparation and Crystal Structures of Ma

Preparation and Crystal Structures of Manganese, Iron, and Cobalt Complexes of the Bis[di(2-pyridyl)methyl]amine (bdpma) Ligand and Its Oxidative Degradation Product 1,3,3-Tris(2-pyridyl)-3H-imidazo[1,5-a]pyridin-4-ium (tpip); Origin of the bdpma Fragility

✍ Catherine Hemmert; Michael Renz; Heinz Gornitzka; Stéphanie Soulet; Bernard Meun 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 2 views

The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo