## Abstract Allyl sulfides and a selenide are metallated and silylated with chloro (pentaβmethyl)disilane. Treatment of the resulting disilanylmethyl sulfides **4** with trimethyloxonium tetrafluoroborate furnishes 1,1βdisilylβ2βalkenes **5** in good yields. Some synthetic possibilities of **5** ar
β¦ LIBER β¦
Preparation of 1-silyl- and 1,3-disilyl-adamantanes
β Scribed by Yi-Ming Pai; Erich Wanek; William P. Weber
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 365 KB
- Volume
- 270
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
1,1-Disilyl-2-Alkenes: Preparation and S
β
HansjΓΌrg Wetter
π
Article
π
1978
π
John Wiley and Sons
π
German
β 189 KB
Preparation and Reaction of 2-Aryl-3-sil
β
Zenichi Ikeda; Koichiro Oshima; Seijiro Matsubara
π
Article
π
2006
π
John Wiley and Sons
β 30 KB
π 1 views
Preparation and cycloaddition reactions
β
Allison R.M. O'Donovan; Michael K. Shepherd
π
Article
π
1994
π
Elsevier Science
π
French
β 357 KB
Palladium-Catalyzed Dimerization Disilyl
β
Jun Terao; Akihiro Oda; Nobuaki Kambe
π
Article
π
2005
π
John Wiley and Sons
β 186 KB
ChemInform Abstract: New Synthesis of 1-
β
B. I. NO; G. M. BUTOV; V. M. MOKHOV; S. A. SAFONOV
π
Article
π
2010
π
John Wiley and Sons
β 28 KB
π 1 views
Synthesis of tetramers of 1,3-adamantane
β
Takashi Ishizone; Hiroyuki Tajima; Shinichi Matsuoka; Seiichi Nakahama
π
Article
π
2001
π
Elsevier Science
π
French
β 72 KB
Novel tetramers of 1,3-adamantane and 5,7-dibutyl-1,3-adamantane were synthesized by the coupling reaction of 3-bromo-1,1%-biadamantane or 3-bromo-5,5%,7,7%-tetrabutyl-1,1%-biadamantane with sodium in n-octane or with magnesium in diethyl ether. Although the former 1,3-adamantane tetramer showed poo