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Preparation of 1-silyl- and 1,3-disilyl-adamantanes

✍ Scribed by Yi-Ming Pai; Erich Wanek; William P. Weber


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
365 KB
Volume
270
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES


1,1-Disilyl-2-Alkenes: Preparation and S
✍ HansjΓΌrg Wetter πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 189 KB

## Abstract Allyl sulfides and a selenide are metallated and silylated with chloro (penta‐methyl)disilane. Treatment of the resulting disilanylmethyl sulfides **4** with trimethyloxonium tetrafluoroborate furnishes 1,1‐disilyl‐2‐alkenes **5** in good yields. Some synthetic possibilities of **5** ar

Synthesis of tetramers of 1,3-adamantane
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Novel tetramers of 1,3-adamantane and 5,7-dibutyl-1,3-adamantane were synthesized by the coupling reaction of 3-bromo-1,1%-biadamantane or 3-bromo-5,5%,7,7%-tetrabutyl-1,1%-biadamantane with sodium in n-octane or with magnesium in diethyl ether. Although the former 1,3-adamantane tetramer showed poo