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Preparation, Magnetic and Structural Study on Oxido-Bridged Diiron(III) Complexes with Open-Chain Tetrapyrrolic 2,2′-Bidipyrrin Ligands

✍ Scribed by Martin Bröring; Silke Köhler; Thomas Ostapowicz; Markus Funk; Clemens Pietzonka


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
575 KB
Volume
2009
Category
Article
ISSN
1434-1948

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (