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Preparation, cure behavior and properties of bis(2-oxazoline)s containing well-defined oligo(tetrafluoroethylene) segments

✍ Scribed by Norbert Steinhauser; Rolf Mülhaupt


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
347 KB
Volume
15
Category
Article
ISSN
1022-1336

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✦ Synopsis


N,W-Bis(2-chloroethyI)-1,1,52-tetrafluoroethane-l,2-dicarboxamide (3a) was prepared by refluxing 15,80 g (57,2 mmol) 2 a in 120 mL thionyl chloride for 16 h. After distilling off the thionyl chloride, the white residue was recrystallized in methanol and dried at 120°C. Yield: 16,12 g (90%); m.p. 164-165OC.

3 305 (N-H), 2960 (C-H), 1700 (C=O), 1560 (N-H), 1200,1175 and 1 135 cm-' (C-F).