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Preparation, crystal structure, magnetic and EPR properties of a heptacoordinated manganese(II) chain of [Mn(bipy) (H2O) (TBD)]n (H2TBD=trans-2-butene diacid, bipy= 2, 2′-bipyridine)

✍ Scribed by Xiang Shi Tan; Dao Feng Xiang; Wen Xia Tang; Jie Sun


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
361 KB
Volume
16
Category
Article
ISSN
0277-5387

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A new eight-coordinate complex of mangan
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The crystal structure of an eight-coordinate manganese(II) compound containing oxamato and water molecules as ligands [Mn(Hoxam) 2 (H 2 O) 4 ], were H 2 oxam=oxamic acid, has been determined by X-ray diffraction on single-crystals. The coordinated oxygen atoms are located at the vertices (corners) o