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Preparation, crystal and molecular structure of trans-dioxo(1,4-dithia-8,11-diazacyclotetradecane)technetium(V) hexafluorophosphate

✍ Scribed by Eugenia Ianoz; Dominique Mantegazzi; Pierre Lerch; Francesco Nicolò; Gervais Chapuis

Book ID: 108324833
Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 531 KB
Volume: 156
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)83506-9

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## Abstract It is shown that ligand **1**, designed to span __trans__‐positions, under appropriate conditions also gives __cis__‐mononuclear complexes of platinum (II). The structure of __cis__‐[PtCl~2~ **(1)**] **(2)** has been determined by single‐crystal X‐ray diffraction. The major distortion f