Preparation, characterization and X-ray analysis of [Co2(Cl)2tpmc](BF4)2. Comparative structural analysis with the complexes having analogous geometries and ligands
✍ Scribed by G. Vučković; S.B. Tanasković; U. Rychlewska; D.D. Radanović; J. Mroziński; M. Korabik
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 412 KB
- Volume
- 827
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHÁ Á ÁF interactions w
V= 1246.97 A', ecalc= 1.311 g . ~r n -~. From 3154 measured reflections (MoK, radiation, h = 0.71073 A) 2128 with I>2u(Z) were used for the refinement of the structure [R(F) [ "I This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie and BASF AG. Ludwiasha