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Preparation, characterization and thermolysis of metal nitrate complexes with 4,4’-bipyridine

✍ Scribed by G Singh; CP Singh; R Frohlich

Book ID: 106444739
Publisher: Springer Netherlands
Year: 2006
Tongue: English
Weight: 669 KB
Volume: 85
Category: Article
ISSN: 0022-5215
DOI: 10.1007/s10973-005-7121-x

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The organotin(IV) chlorides R n SnCl 4-n (n = 3, R = Ph, PhCH 2 , n-Bu; and n = 2, R = n-Bu, Ph, PhCH 2 ) react with 4,4 -bipyridine (4 4-bpy) to give [(Ph 3 SnCl) 2 (4,4 -bpy) [(n-Bu) 3 SnCl] 2 (4,4 -bpy) (3), [(n-Bu) 2 SnCl 2 (4,4 -bpy)] ( 4), [Ph 2 SnCl 2 (4,4 -bpy)] ( 5), and [(PhCH 2 ) 2 SnCl 2