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Preparation, characterization, and reactions of novel iron(III) porphyrin dication complexes

โœ Scribed by Tsurumaki, Hiroshi; Watanabe, Yoshihito; Morishima, Isao


Book ID
126117861
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
528 KB
Volume
115
Category
Article
ISSN
0002-7863

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A novel insulin-disubstituted Co(III) protoporphyrin IX, CoPI, where I is insulin and CoP is Co(III) protoporphyrin IX, was prepared by covalently coupling the propionate groups on the porphyrin ring to the ฮต-amino groups of B29-Lys on insulin via amide linkages. The FTIR spectra in the amide I regi