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Preparation, characterization and crystal structures of manganese(II), iron(III) and copper(II) complexes of the bis[di-1,1-(2-pyridyl)ethyl]amine (BDPEA) ligand; evaluation of their DNA cleavage activities

✍ Scribed by Catherine Hemmert; Marguerite Pitié; Michael Renz; Heinz Gornitzka; Stéphanie Soulet; Bernard Meunier


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
153 KB
Volume
6
Category
Article
ISSN
1432-1327

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The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo

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## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t