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Preparation, Characterization, and Catalytic Properties of Polymer-Stabilized Ruthenium Colloids

✍ Scribed by Weiyong Yu; Manhong Liu; Hanfan Liu; Xiaoming Ma; Zhijie Liu

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
439 KB
Volume
208
Category
Article
ISSN
0021-9797

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✦ Synopsis

Poly(N-vinyl-2-pyrrolidone) (PVP)-stabilized ruthenium colloids were prepared by NaBH 4 reduction at room temperature and characterized by transmission electron microscopy and x-ray photoelectron spectra. The average diameters of the colloids were 1.3-1.8 nm with ‫؍‬ 0.4 -0.7 nm with respect to the preparation conditions. The PVP-stabilized ruthenium colloids were used as catalysts in the hydrogenations of cyclooctene and n-heptene and the selective hydrogenation of citronellal to citronellol.

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