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✦ LIBER ✦
Preparation and Synthetic Applications of Enantiopure (2 S ,3 S )- or (2 R ,3 S )-2-Halomethyl-1,2-epoxyalkan-3-amines
✍ Scribed by Barluenga, José; Baragaña, Beatriz; Concellón, José M.
- Book ID
- 127118404
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 105 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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The litle anlinomethyl (5) and amino (6) alcohols, which are of interest as intermediates in the synthesis of carbocyclic analogues of nucleosides, were prepared from (+)-camphoric acid via methyl (1S,3R)-3-carbamoyl-2.3.3-trimelhylcyclopel~tane earboxylale (8). Direct reduction of S gave 5 in 26% y
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