Cellulose hydrogels have been synthesized by reacting solutions of cellulose xanthate with different amounts of epichlorohydrin (0-24% w/w on cellulose) after which the cellulose was regenerated. The weight fraction of crystalline cellulose, determined by density measurements, decreases with the ext
Preparation and swelling of polymeric hydrogels
β Scribed by A. G. Andreopoulos
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 395 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Hydrogel polymers find extensive biomedical applications combining the properties of hydrophilic and crosslinked materials. In this work, poly(methacrylic acid) hydrogels were prepared by the copolymerization of methacrylic acid with varying amounts of 1,4-butanediol dimethacrylate. The polymerization reaction was followed by viscometric measurements and the swelling properties of the samples prepared were also investigated. Alkaline treatment of the hydrogels was performed, to define the changes induced. Finally, a correlation between swelling data, derived from loosely crosslinked samples, led to the determination of the interaction parameter of the system poly(methacrylic acid)-water.
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