✦ LIBER ✦

Preparation and structures of chiral mono and bis ortho-aminoalkyl-substituted 1,1′-trichalcogena[3]ferrocenophanes

✍ Scribed by Shin-ichi Fukuzawa; Daisuke Wachi

Book ID: 102229987
Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 165 KB
Volume: 17
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20189

No coin nor oath required. For personal study only.

✦ Synopsis

We prepared a series of mono and bis ortho-aminoalkyl-substituted chiral trichalcogena[3]ferrocenophanes by dilithiation of mono-and bisaminoferrocenes and subsequent reaction with sulfur and selenium in moderate yields. The X-ray crystallographic analyses of triselena [3]ferrocenophanes revealed that the bridge selenium atom was directed toward to the ortho-substituent (endo). In the bis-type ferrocenophanes, bridge inversion was not detected by 1 H NMR because they would be homomeric.

📜 SIMILAR VOLUMES

Synthetic, structural and electrochemica

Synthetic, structural and electrochemical studies on some ferrocenylazines: crystal structures of [4](1) (1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane and [42](1,1′) bis(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane

✍ A.G. Osborne; M. Webba da Silva; M.B. Hursthouse; K.M.A. Malik; G. Opromolla; P. 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 702 KB

Preparation, Structure, and Unique Redox

Preparation, Structure, and Unique Redox Properties of Mono-, Bis-, and Tris(diarylmethylene)-1,3,5-trithianes and Related Compounds

✍ Suzuki, Takanori; Yoshino, Tsuyoshi; Nishida, Jun-ichi; Ohkita, Masakazu; Tsuji, 📂 Article 📅 2000 🏛 American Chemical Society 🌐 English ⚖ 126 KB

Heterocyclic Amplifiers of Phleomycin. V

Heterocyclic Amplifiers of Phleomycin. VIII. Mono- Bis-(5'-substituted 1',3',4'-thiadiazol-2'-yl)pyridines and Mono(5'-substituted 1',3',4'-thiadiazol-2'-ylmethyl)pyridines

✍ Barlin, GB 📂 Article 📅 1985 🏛 Commonwealth Scientific and Industrial Research Or 🌐 English ⚖ 363 KB

ChemInform Abstract: Preparation, Struct

ChemInform Abstract: Preparation, Structure, and Unique Redox Properties of Mono-, Bis-, and Tris(diarylmethylene)-1,3,5-trithianes and Related Compounds.

✍ Takanori Suzuki; Tsuyoshi Yoshino; Jun-ichi Nishida; Masakazu Ohkita; Takashi Ts 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Preparation and structure of crosslinked

Preparation and structure of crosslinked poly(methyl methacrylate-co-1,3-bis-(methacryloxymethyl)-1,1,3,3-tetramethyl disiloxane)

✍ Wu-Huang Michael Yang; Nikolaos A. Peppas 📂 Article 📅 1983 🏛 Springer 🌐 English ⚖ 209 KB

Synthesis and Structures of Lithium and

Synthesis and Structures of Lithium and Potassium Complexes of Phosphanyl-Substituted Bis[1,3-bis(trimethylsilyl)cyclopentadienyl]yttriates

✍ Westerhausen, Matthias; Schneiderbauer, Stefan; Makropoulos, Nikolaos; Warchhold 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 142 KB