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Preparation and structure of iron carbidocarbonyl cluster [(C2H5)4N][Fe5RhC(CO)16]

✍ Scribed by V. E. Lopatin; N. M. Mikova; S. P. Gubin


Book ID
112444459
Publisher
Springer
Year
1983
Tongue
English
Weight
212 KB
Volume
32
Category
Article
ISSN
1573-9171

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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit