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Preparation and structural studies of lithium substituted nickel phosphorus trisulphide, Li2NiP2S6

✍ Scribed by S.N. Patel; A.A. Balchin


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
255 KB
Volume
14
Category
Article
ISSN
0167-2738

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One-pot reaction of acetaldehyde, KSCN and POCl3 affords 2,6dimethyl-4-isothiocyanato-1,3dioxane 4 in good yield. Compound 4 reacts with primary amines to give crystalline re/-2S,4R,6S-2,6dimethyl-4-(N'substituted thiourefdo)-1,3dioxanes 5. The obtained thioureas 5 with axial thioureido group are sp