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Preparation and Structural Characterization of [K(18-crown-6)]+ Salts of [RNSN]− Anions and the [NSN]2− Dianion

✍ Scribed by Tobias Borrmann; Enno Lork; Rüdiger Mews; Makhmut M. Shakirov; Andrey V. Zibarev


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
229 KB
Volume
2004
Category
Article
ISSN
1434-1948

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18-Crown-6 and Titanium Tetrafluoride −
✍ T. Stanley Cameron; Andreas Decken; Evgeny G. Ilyin; Grigori B. Nikiforov; Jack 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views

## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__