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Preparation and structural characterisation of the cation-π complexes [{(Me 3 Si) 2 NK} · ( t Bu-C 6 H 5 )] 2 and [{(Me 3 Si) 2 NK} · (Me 3 -C 6 H 3 )] 2

✍ Scribed by Randazzo, John B.; Morris, J. Jacob; Henderson, Kenneth W.

Book ID
120000871
Publisher
IOS Press
Year
2006
Tongue
English
Weight
440 KB
Volume
5
Category
Article
ISSN
1024-1221

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The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we