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Preparation and spectroscopic studies of antimony(III) and bismuth(III) halodithiocarbamate derivatives

✍ Scribed by Aleardo Giusti; Carlo Preti; Giuseppe Tosi; Paolo Zannini


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
735 KB
Volume
98
Category
Article
ISSN
0022-2860

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## Abstract Chlorotriflates of antimony and bismuth Cl~__n__~M(OSO~2~CF~3~)~3βˆ’~~__n__~ (__n__ = 1 or 2) are believed to be metallic intermediates of major importance in Friedelβˆ’Crafts reactions that use Bi(OSO~2~CF~3~)~3~, Sb(OSO~2~CF~3~)~3~, the systems BiCl~3~/CF~3~SO~2~OH or SbCl~3~/CF~3~SO~2~OH