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Preparation and spectroscopic characterization of two HoCl3–galactitol complexes and one ErCl3–galactitol complex

✍ Scribed by Xiaohui Hua; Qinghua Pan; Lei Yu; Junhui Xue; Limin Yang; Yizhuang Xu; Guozhong Zhao; Weihong Li; Zheming Wang; Jinguang Wu; Kexin Liu; Jia’er Chen

Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
861 KB
Volume
998
Category
Article
ISSN
0022-2860

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Alditols form stronger complexes with Nd3+, Sm3+, and Eu3+ than with La3+ cations, but weaker ones with the higher lanthanides. There is a clear relationship between ionic radii and stability constants. Chromatographic ion-exchange columns can be smaller when prepared with Nd3\* rather than the usu