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Preparation and some reactions of difluoroborane

โœ Scribed by Coyle, Thomas D.; Cooper, J.; Ritter, John J.


Book ID
126913241
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
865 KB
Volume
7
Category
Article
ISSN
0020-1669

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Preparation and reactions of some organo
โœ Colin Eaborn; Yousef Y. El-Kaddar; Paul D. Lickiss ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 974 KB

from traces of water). Reaction of 1 with KSCN in MeCN gives exclusively the substitution product TsiSiMe,NCS, but CsF and NaN,, which are only very slightly soluble, promote very predominant isomerization. Possible mechanisms of the isomerizations are discussed. Cyanate is a markedly better leaving