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Preparation and Ring-Opening Polymerization of 2-tert-Butyl-7-oxabicyclo[2.2.1]heptane

✍ Scribed by Saegusa, Takeo; Motoi, Masatoshi; Suda, Hirosh


Book ID
125974294
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
449 KB
Volume
9
Category
Article
ISSN
0024-9297

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## Abstract A new unsaturated bicyclic ether, 2‐methylene‐7‐oxabicyclo[2.2.1]heptane (4) was synthesized by successive Diels‐Alder addition of furan to acrylonitrile, hydrogenation of cyano compound 5, and Hofmann degradation of the quaternary ammonium hydrate 7 derived from the amine 6. Cationic p