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Preparation and Resolution of a Five-Coordinate Complex: Bisacetylacetonepropylenediiminooxovanadium(IV)

✍ Scribed by Ramaiah, K.; Anderson, F. E.; Martin, Dean F.

Book ID
126111062
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
259 KB
Volume
3
Category
Article
ISSN
0020-1669

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The dichlorodihydridoruthenium (IV) compound [RuH 2 Cl 2 -were obtained. The phenylvinylidene complex [RuCl 2 (=C= CHPh)(PCy 3 ) 2 ] (15) was prepared from phenylacetylene and (PiPr 3 ) 2 ] (4) was prepared from [RuCl 2 (C 8 H 12 )] n (3), PiPr 3 , and H 2 in 2-butanol via the chlorohydridoruthenium