Preparation and Reactivity of Solvated Distonic Ions and Ionized Enols in the Gas Phase
✍ Scribed by Troude, V.; van der Rest, G.; Mourgues, P.; Audier, H. E.
- Book ID
- 127096493
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 93 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The cation‐radical of 2‐hydroxyoxol‐2‐ene (**1**^+·^) represents the first lactone enol ion whose structure and gas‐phase ion chemistry have been studied by experiment and theory. Ion **1**^+·^ was generated by the McLafferty rearrangement in ionized 2‐acetylbutane‐4‐lactone and charact
Sumnary: The en01 form of acetophenone was generated in the gas phase and its ionization energy was determi@ as 8.01 + 0.03 eV. The heat of formation of the en01 was assessed as -46 + 6 kJ.nol . The enoi is destabilized against acetophenone by 41 kJ.mol-1. -1-Phenylethenol (L) was first detected in