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Preparation and reactions of a disilyne synthon, 7,7′-bis(7-methyl-1,4,5,6-tetraphenyl-7-sila-2,3-benzo-norbornadiene)

✍ Scribed by Akira Sekiguchi; Steven S. Zigler; Kenneth J. Haller; Robert West


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
457 KB
Volume
107
Category
Article
ISSN
0165-0513

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✍ Christine Gottardo; Stephen Fratpietro; Alan N. Hughes; Mark Stradiotto 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB 👁 1 views

The stable 7-phosphanorbornadiene derivative, 2,3-benzo-1,4,5,6,7-pentaphenyl-7-phosphabicyclo[2.2.1]hepta-2,5-diene-7-oxide (1) was synthesized in 45% yield via the Diels-Alder reaction of pentaphenylphosphole oxide and benzyne. The reaction occurs specifically to give a single isomer, which was ch