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Preparation and Reactions of 3,4-Bis(tributylstannyl)-2(5 H )-furanone

✍ Scribed by Mabon, Ross; Richecœur, Alexandre M. E.; Sweeney, J. B.

Book ID
127101996
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
90 KB
Volume
64
Category
Article
ISSN
0022-3263

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Synthesis of 4-alkyl-3-bromo-2(5H)-furan
Synthesis of 4-alkyl-3-bromo-2(5H)-furanones and unsymmetrically disubstituted 3,4-dialkyl-2(5H)-furanones by palladium-catalyzed cross-coupling reactions
✍ Fabio Bellina; Chiara Anselmi; Renzo Rossi 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 65 KB

Easily available 3,4-dibromo-2(5H)-furanone undergoes a regioselective cross-coupling reaction with alkylboronic acids in the presence of catalytic amounts of PdCl2(MeCN)2 and AsPh3 and a large molar excess of Ag2O to provide the corresponding 4-alkyl-3-bromo-2(5H)-furanones in satisfactory yields.