Preparation and reaction of compounds related to 2,2,4,4-tetramethylpentane-3-thiol[di(tert-butyl)methanethiol]
β Scribed by Buter, J.; Kellogg, Richard M.
- Book ID
- 126833084
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 539 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
trrf-Butyl and 2,6-di(tert-butyl)-4-methylphenyl (RHT) cyclopropanecarboxylates (4, 6, 24, 25) are lithiated with LiN(i-Pr), and t -BuLi, respectively. Reactions with alkyl halides, aldehydes, acyl chlorides, and heteroelectrophiles give a-substituted BHT esters which can be cleaved (t-BuOK/H,O/THF)
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