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Preparation and properties of (μ 3 -Thio)(μ 3 -organophosphido)tris(tricarbonyliron)(2Fe-Fe) complexes

✍ Scribed by Seyferth, Dietmar; Withers, Howard P.


Book ID
127091910
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
866 KB
Volume
1
Category
Article
ISSN
0276-7333

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The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri