Preparation and properties of transparent cellulose hydrogels
β Scribed by Hidenao Saito; Akihiko Sakurai; Mikio Sakakibara; Hiroshi Saga
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 127 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a waterβmiscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. Β© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020β3025, 2003
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Xylan with glucuronic acid functionalities, separated from birchwood, was converted into hydrogels by dissolving it together with chitosan in acidic conditions. The hydrogels were formed at certain xylan/chitosan compositions. The mechanism of the gel formation was investigated with FTIR. Complexati