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Preparation and properties of polysilsesquioxanes. Function and characterization of coating agents and films

✍ Scribed by Yoshimoto Abe; Keiko Kagayama; Norihiro Takamura; Takahiro Gunji; Toshio Yoshihara; Nobuko Takahashi


Book ID
117150149
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
711 KB
Volume
261
Category
Article
ISSN
0022-3093

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## Abstract **Summary:** Network polysilsesquioxane spheres made solely of poly(vinylsilsesquioxane) (PVSQ) and poly(3‐mercaptopropylsilsesquioxane) (PMPSQ) were prepared from heterogeneous mixtures of triethylamine (TEA), water, and either vinyltrimethoxysilane (VTMS), or 3‐mercaptopropyltrimethox

Preparation and properties of polysilses
✍ Norihiro Takamura; Takahiro Gunji; Hideaki Hatano; Yoshimoto Abe πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 211 KB πŸ‘ 1 views

Polymethylsilsesquioxane (PMS) and polyvinylsilsesquioxane (PVS) were prepared by acid-catalyzed controlled hydrolytic polycondensation of methyl-and vinyltrimethoxysilane (MTS and VTS), respectively. The spinnabilities and molecular weights of polysilsesquioxanes were easily controlled by the react