Complex formation between a-(5-ch1oro-8-quinolinoxy)-o-(5-chloro-8-quinoliny1)poly (oxyethylene) (POE\*) and Fe3+ ions as well as the formation of interpolymer complexes between POE\*
Preparation and properties of poly(oxyethylene)s with 5-chloro-8-quinolinoxyl end-groups
β Scribed by I. Rashkov; N. Angelova; N. Manolova
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 479 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0014-3057
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β¦ Synopsis
Chemical modification of ~t,to-dichloropoly(oxyethylene)s (MW from 400 up to 3000), for obtaining poly(oxyethylene)s with 5-chloro-8-quinolinoxyl end-groups, is described. The products have been characterized by GPC, IH-NMR and electronic spectra. Their ability to form complexes with polymers of acrylic and methacrylic acids in dilute aqueous solution has been investigated. 5-Chloro-8quinolinoxyl end-groups stabilize the polycomplexes. It has been shown that, in the polycomplexes, the N-atom from the quinoline group is not protonated. The fact has been explained by the localization of the 5-chloro-8-quinolinoxyl end-groups mainly in the hydrophobic domains of the complexes.
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